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The IUP Journal of Chemical Engineering
Kinetic Modeling of Biosorption of Cadmium by Syzygium cumini (L.) from Aqueous Solution
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In this study Syzygium cumini (L.) was used as a biosorbent to remove Cadmium (Cd)(II) from aqueous solution. A kinetic study for the residual concentration of metal ions was determined after contacting up to 60 min. Equilibrium was established in about 20 min for Cd(II). The maximum uptake of Cd(II) was 36.363 mg/g for Syzygium cumini (L.). In order to examine the control mechanism of biosorption processes, pseudo-first order and pseudo-second order kinetic models were used to test the experimental data and kinetics was found to be the best fit with the pseudosecond order kinetic model

 
 

Industrial activities represent an important pollutant source nowadays, mainly concerning the addition of heavy metals in the soil. This contributes to a significant increase in the concentration of those ions in waters representing an important source of contamination of aquatic bodies, especially when it is considered that such ions can be disseminated through the food chain (OECD, 1996).

Cadmium (Cd)(II) is a metal widely used in industries such as metal plating, metallurgical alloying, mining, ceramics and other industrial operations (ATSDR, 1997). (Cd)(II) toxicity may be observed in a variety of syndromes and effects including renal dysfunction, hypertension, hepatic injury, lung damage and teratogenic effects (Owens, 1994). Hence it is important to remove trace of (Cd)(II) from drinking water, or to remove cadmium from waste waters before they are The IUP Journal of Chemical Engineering, Vol. III, No. 2, 26 2011 discharged into receiving water bodies. The conventional methods for treatment of Cd(II) in wastewater include: precipitation, adsorption with activated carbon, ion exchange, membrane processes, oxidation and reduction (Matheickal and Yu, 1996; and Martins et al., 2004).

These methods are expensive and often involve the use of chemicals and generate large amounts of sludge. Biosorption is a process that utilizes low-cost biosorbents to sequester toxic heavy metals (Chang and Hong, 1994). The advantages of biosorption over the conventional methods are low operating cost, selectivity for specific metal, short operational time and no chemical sludge (Chu et al., 1997).

 
 

Cadmium (II); Syzygium cumini (L.); Biosorption; Kinetics studies, Chemical Engineering Journal, Cross Linked Pva Membranes, Pervaporation Catalytic Membrane Reactor, Membrane Separation Process, Esterification Reactions, Plant Scale Production, Catalytic Membranes, Kinetic Model Equations, Regression Analysis, Pervaporation Reactors.