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The IUP Journal of Chemical Engineering
Comparative Study on the Adsorption Kinetics of Cd (II) and Cu (II) Metal Ions Onto Eggshell Powder
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The removal of Copper (Cu) (II) and Cadmium (Cd) (II) ions from aqueous solutions by adsorption on hen eggshells was investigated depending on the pH, sorbent dosage, contact time, initial metal concentration and sorbent size. The optimum values of pH were found to be 6 for both the metal ions. The equilibrium contact time was determined to be 60 m for the adsorption of Cu (II) ions and 90 m for the adsorption of Cd (II) ions. From the initial concentrations, the constant for the Freundlich, Langmuir and Redlich Peterson isotherms was calculated at room temperature. It was found that biosorption of Cd (II) and Cu (II) ions onto the eggshell were better suitable to Langmuir, than Freundlich or Redlich Peterson model. The maximum biosorption capacity of hen eggshell for Cd was 34.39 mg/g and 32.02 mg/g for Cu. The kinetic experimental data were properly correlated with the second order kinetic model for both metal ions. The present data confirms that hen eggshells may be used as efficient biosorbent for the removal of Cd (II) and Cu (II) ions from aqueous solution.

 
 

Industrial activities represent an important pollutant source nowadays, mainly concerning the addition of heavy metals in the soil. This contributes to a significant increase in the concentrations of those ions in waters which is an important source of contamination of the aquatic bodies, especially when it is considered that such ions can be disseminated through the food chain (Paim et al., 2003).

Heavy metal contamination exists in aqueous waste streams from diverse industries, such as metal plating, mining, tanneries, painting, car radiator manufacturing, batteries, as well as agricultural sources where fertilizers and fungicidal sprays are intensively used. Copper (Cu), Zinc (Zn), Mercury (Hg) and Cadmium (Cd) are harmful wastes produced by industries that pose a risk to the contamination of groundwater and other water resources. Heavy metals are not biodegradable and tend to accumulate in living organisms, causing various diseases and disorders (Friberg et al., 1974; Baik et al., 2002; Guo et al., 2002; Ngah et al., 2002; Matis et al., 2003; Yu, 2005; and Prasertet al., 2006). For example, Cd causes serious renal damage, anemia, hypertension and itai -itai (a type of disease caused by Cd contamination).

The reduction of pollutant to an acceptable level is necessary when toxic metals are present in the aquatic system (Gupta et al., 2003). In this regard, several conventional wastewater treatment technologies, such as ion exchange, chemical precipitation, evaporation, membrane filtration, reverse osmosis, electrodialysis and adsorption were developed and used successfully. Application of such traditional treatment techniques needs enormous cost and continuous input of chemicals which becomes impracticable and uneconomical, and causes further environment damage.

 
 

Chemical Engineering Journal, Metal Ions Onto Eggshell Powder, Heavy Metal Contamination, Water Resources, Traditional Treatment Techniques, Aquatic System, Equilibrium Biosorption Data, Biosorption Processes, Biomass Concentration, Biosorption Equilibrium, Biosorption Isotherm, Redlich Peterson Models.