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The IUP Journal of Chemical Engineering
Treatment of Anaerobically Digested Distillery Effluent by Aspergillus niger
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The objective of the study was to evaluate the potential options for further reduction of the persistent dark brown color and Chemical Oxygen Demand (COD) from the anaerobically digested distillery effluents collected from the Lord's distillery, Nandganj, Ghazipur, India. Chemical coagulation followed by aerobic degradation using Aspergillus niger was evaluated for its effectiveness in reducing the COD and color from the anaerobically treated effluents. Various coagulants such as potash alum, ferric chloride and aluminum chloride have been used during the experiments. The biological parameters such as nutrient concentration, initial pH and temperature were optimized. The results depict that coagulation alone rendered 78.5% COD reduction as well as 92.45% color reduction. A maximum of 65% of the remaining color could be removed by 10% (v/v) Aspergillus niger inoculums in effluent sample (product of coagulation) in batch mode under sterile condition. The observation can be similarly used in a distillery to improve the efficiency of aerobic treatment.

 
 

Many industries, such as dyestuffs, textile, paper and plastics, use dyes in order to color their products and also consume substantial volumes of water. As a result, they generate a considerable amount of colored wastewater. It is recognized that public perception of water quality is greatly influenced by the color.

Color is the first contaminant to be recognized in wastewater (Banat et al., 1996). The presence of very small amounts of dyes, such as methylene blue, malachite green, crystal violet, methyl orange, etc., in water (less than 1 ppm for some dyes) is highly visible and undesirable (Robinson et al., 2001). Many of these dyes are also toxic and even carcinogenic and this poses a serious hazard to aquatic living organisms (O'Neill et al., 1999). The major effect of dyes on humans is that they cause severe mutagenic and carcinogenic effects. Due to increasingly stringent restrictions on the organic content of industrial effluents, it is necessary to eliminate dyes from wastewater before it is discharged (Wang et al., 2008).

In the past three decades, several physical, chemical and biological decolorization methods were reported. A few methods have been accepted by the paper and textile industries (Ghoreishi and Haghighi, 2003). Amongst the numerous techniques of dye removal, adsorption is the procedure of choice and gives the best results, as it can be used to remove different types of coloring materials (Jain et al., 2003). In the present investigation, untreated Psidium guajava L.f. leaf powder was examined in an attempt to remove Congo red from its aqueous solution.

Congo red is the sodium salt of benzidinediazo-bis-1-naphtylamine-4-sulfonic acid. It is a secondary diazo dye. Congo red is water soluble, yielding a red colloidal solution; its solubility is better in organic solvents such as ethanol.

 
 

Chemical Engineering Journal, Distillery effluent, Coagulation, Melanoidin, Aerobic Treatment, Aspergillus Niger, Chemical Oxygen Demand, COD, Aquatic Ecosystem, Biological Oxygen Demand, BOD, Microbial Decolorization, Potato Dextrose Agar, PDA, Primary Distillery Effluent, PDE, Physico-Chemical Treatment.