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The IUP Journal of Chemistry
Acoustical Studies of Some Derivatives of 4-Amino Benzoic Acid in 1,4-Dioxane and Dimethyl Formamide at 308.15 K
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The derivatives of 4-amino benzoic acid have been synthesized and characterized by TLC, IR and NMR spectral data. The ultrasonic velocity, density and viscosity of all these compounds were measured in 1, 4-dioxane (DO) and dimethylformamide (DMF) at 308.15 K. Various acoustical properties, such as specific impedance (Z), isentropic compressibility (cS), Rao's molar sound function (Rm), van der Waal's constant (b), molar compressibility (W), inter-molecular free length (Lf), relaxation strength (r), relaxation time (t) and classical absorption coefficient [(a/f2)Cl] were calculated. The results have been interpreted in terms of molecular interaction occurring in the solutions.

 
 
 

Ultrasonic techniques are known to be non-destructive and have applications in various fields. In industries, ultrasonic waves are used for polishing and cutting of steel (Schneider et al., 2008), non-destructive material testing (Hanson, 1986), welding of metals (Langenecker, 1966), etc. They are also used in the medical field for the diagnosis of various diseases, such as vascular diseases (Vogelberg et al., 1987), cancer (Liu et al., 2008), brain disorders (Dussik, 1952) and dental disorders (Zietowska et al., 1976), etc. These ultrasonic waves are applicable in the food industry (Brogna et al., 1998; and Sahi and Sun, 2005), food processing (Lee and Cha, 2009) and analyzing the milk composition (Liu et al., 2003), etc. Further, they are used in material science for studying various properties of solids, such as compressibility (Shung and Reid, 1978), specific heat ratios (Halstenberg et al., 1998) and elasticity (Fahey et al., 2009).

In continuation with our previous work (Baluja and Oza, 2001; Baluja, 2006; and Baluja, 2008), in the present paper, we have used this technique for a better understanding of some solutions. For this, density, viscosity, and ultrasonic velocity of solutions of schiff bases of 4-amino benzoic acid have been measured in 1, 4-dioxane (DO) and dimethylformamide (DMF) at 308.15K over a wide concentration range.

The experimental data was used for the evaluation of various thermodynamic and acoustical parameters by which molecular interactions in solutions are interpreted.

 
 
 

Chemistry Journal, Dimethyl Formamide, Ultrasonic Techniques, Ultrasonic Waves, Molecular Interactions, Acoustical Properties, Echocardiographic Techniques, Ultrasonic Velocity, Solvent Molecules, Vascular Diseases, Milk Composition.